By Atul Tiwari
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The chain flexibility arises from the very large bond angle of the Si–O–Si linkages and the low bending force constant for this linkage. The glass transition temperature, Tg of PDMS, which reflects the ease of segmental motion along the chain, is typically less than −120°C. The ability to spread and the intrinsic hydrophobicity of silicones make them among the lowest surface-energy compounds known . Hence, silicones are used as release agents to prevent adhesion in many applications. When silicones are chemically combined with hydrophilic species such as cationic species or poly(ethylene oxide), very interesting surfactant properties arise.
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P. R. M. Reynders, Review of aging and recovery of silicone rubber insulation for outdoor use, IEEE Transactions on Dielectrics and Electrical Insulation, Vol. 6, Issue 5, p. 620–631, Oct. 1999. H. Janssen, A. C. Karner, LMW components in silicone rubber and epoxy resins, in: 11th International Symposium on High-Voltage Engineering (ISH 99), London 1999. W. Lu, H. Janssen, A. C. 727–730. J. Zhidong, G. Zhicheng, G. Haifeng, Flashover mechanism of RTV coated insulators, Annual Report Conference on Electrical Insulation and Dielectrics Phenomena, p.
Concise Encyclopedia of High Performance Silicones by Atul Tiwari