By Allen J. Bard, Martin Stratmann, Fritz Scholz, Visit Amazon's Christopher J. Pickett Page, search results, Learn about Author Central, Christopher J. Pickett,
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Additional info for Encyclopedia of Electrochemistry, Volume 7a: Inorganic Electrochemistry (Encyclopedia of Electrochemistry)
8 V The aqua complexes of Fe2+ and Fe3+ , which are present in acid solutions, can hydrolyze to FeOH+ , Fe(OH)2+ , Fe(OH)2 + , and other ions at higher pH values, and the respective hydroxides precipitate. Weak anion complexes such as FeSO4 , FeSO4 + , or FeCl2+ can also be formed. 07 Ru), OS: +8, +7, +6, 44 +4, +3, +2, 0; IE: 711 kJ mol−1 . 99 V (calcd) RuO4 − (aq) + 3e− + 4H+ −−−→ RuO2 (s, hydr) + 2H2 O The formation of polymeric and mixedvalence complexes also occurs in aqueous solutions. 59 V versus Fc+ /Fc Formal potentials of ruthenium metallocenes can be found in Refs 42–44.
6 × 10−19 Complex equilibria The information about the composition and stability of several Cu2+ complexes with nitrogen-containing and polyhydroxylic ligands can be found in Refs 50–65. 4 kJ mol−1 . 3, (2895) kJ mol−1 . 154 V  R¨ontgenium ( 111 Rg) No data are available. 1, 1733, 3831 kJ mol−1 . 5, 1631, 3644 kJ mol−1 . 53 × 10−8 Data for several Cd2+ complexes can be found in Refs 65, 66. 59 80 Hg), OS: +2, +1, 0; IE: 1007, 1809, 3300 kJ mol−1 . 7 kJ mol−1 . g. B6 X6 2− (X = Cl, Br, I)) can be found in Ref.
This is mainly due to the formation of oxides and hydride ﬁlms on the Ti surface, which causes it to behave as a noble metal. Titanium dissolves rapidly only in HF. 224 40 Zr), OS: +4, +3, +2, +1, 0; IE: 661 kJ mol−1 . 49 72 Hf), OS: +4, +3, +2, +1, 0; IE: 681 kJ mol−1 . 57 V (calcd) The experimental determination of E 0 values is hindered by the formation of surface oxides and polymeric species with oxo and hydroxo bridges in the solution. Hydrolysis practically always takes place even in strongly acidic media.
Encyclopedia of Electrochemistry, Volume 7a: Inorganic Electrochemistry (Encyclopedia of Electrochemistry) by Allen J. Bard, Martin Stratmann, Fritz Scholz, Visit Amazon's Christopher J. Pickett Page, search results, Learn about Author Central, Christopher J. Pickett,